Cellular signals travel over greater distances than WiFi signals, so potentially more people could be monitoring cellular signals if they have the right equipment.
Unless you are on an old style analogue network, then the cellular signal is encrypted. 3G and 4G signals use digital networks, so they are encrypted. The cellular device will use a number of local towers depending upon how good the signal is to each tower. The actual signal will jump from tower to tower probably several times per second, although this does not help protect signals going from the device to the network as the device is in a single location. The signals also jump backwards and forwards between different channels in the cellular band. All this helps the phone or device maintain a reasonable connection with the network even if certain mast and frequency combination hit a null spot as far as the wireless signal is concerned.
WiFi is used over a much smaller radius from the base station (the router). With WPA2 (personal) encryption and a good long obscure pass phrase using numbers, letters and punctuation then the network is reasonably secure.
Both WiFi and Cellular networks require specialist equipment and software to hack in to. With a powerful super-computer it will normally take many months to hack in to either network successfully. If your router offers WPS setup for connecting devices, then this should be disabled. WPS has a known flaw that allows hackers on to the network fairly quickly while WPS is active.
Unless you are doing something illicit or top secret, then you should not need to worry about the relative security offered by WiFi or Cellular connections.
I hope this helps.